Compared with traditional inorganic (e.g. Ning the importance of specific metal-ligand affinity in metaldirected self-assembly.Ĭoordination polymers are a class of superior inorganic-organic hybrid materials that hold promises for a wide range ofĪpplications such as fuel storage, gas separation, and catalysisĮtc. Tendency of silver for aromatic nitrogen and thioether sulfur atoms. Compared to zero-dimensional 1, the extension to one-dimensional 2 is considered to result from the specific affinity between Ag+Īnd the ligand 4-MTPP that is attributed to the strong coordinating For AgNO3, a unique one-dimensionalĭouble-chain structure (2) was obtained with the Ag–N distances vary. For Cu(NO3)2, a discrete mononuclear CuII coordination compound, (1), resulted that is exclusivelyīased on Cu–N coordination. The self-assembly of 4-MTPP with Cu(NO3)2 and AgNO3 was structurally investigated. Keywords: Self-assembly Silver Metal-ligand affinity Thioether Crystal structureĪbstract. Hai-Bin Zhu,* Ru-Yu Shan, Wen-Na Yang, and Shao-Hua Gou* From Zero-dimensional to One-dimensional: Use of Metal-Ligand Affinity in
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